The effect everyone has felt
A particular smell catches you in a hallway and you are, for a moment, fifteen again. A cousin's house. A high school locker room. A grandparent's kitchen. The memory does not arrive in pieces. It arrives whole, with weather and emotion attached.
Other senses can do something like this, but rarely as fast or as completely. A song sometimes returns a year. A photograph sometimes returns a face. A smell often returns a room. The reasons sit in the architecture of the brain.
Why smell goes deeper
Most sensory information passes through a relay station in the brain called the thalamus before being routed to the relevant processing areas. Smell is the exception. Olfactory information bypasses the thalamus and connects directly to the limbic system, including the amygdala (which processes emotion) and the hippocampus (which is central to memory).
That direct connection is one of the reasons smell carries such an emotional and autobiographical charge. The signal arrives at the emotion-and-memory machinery first, before the conscious-recognition machinery has a chance to label it. We feel something about a scent before we know what the scent is.
Studies of olfactory memory generally find that smell-cued memories tend to be older, more specific, and more emotionally charged than memories cued by other senses. The Proust effect, named for the famous madeleine passage in Swann's Way, has been studied empirically since at least the 1970s, and the basic finding has held.

Why scent feels so personal
Beyond the wiring, smell has another property that gives it autobiographical weight. We tend to encounter most scents in specific contexts, attached to specific people, in specific rooms, at specific ages. There is rarely a generic encounter with a smell the way there is with, say, the color blue.
Because of that, almost every scent a person encounters builds an episodic memory rather than a semantic one. Episodic memories are richer, more sensory, and more emotionally textured than semantic memories. A scent does not get filed in the brain the way a word does.
This is part of why a perfume that someone wore through one season of their life can become inseparable from that season for everyone close to them. The scent and the period have been encoded together.
The cultural weight of perfume
The perfume industry has known this for centuries, even before the neuroscience caught up. The structure of fine perfumery (top notes, heart notes, base notes) is built around the way scent unfolds across time. A perfumer is not composing a flat impression. They are composing a sequence the wearer's memory will eventually fold into a single name.
The idea of a signature scent has carried serious weight in personal care for nearly a hundred years, often with mixed effects. The most enduring fragrances tend to be the ones that, over time, become inseparable from the people who wore them rather than the campaigns that introduced them.
It is worth noting where the limit of this argument sits. A scent does not make the person. It becomes associated with them. The thing being remembered is still the person.
What this means in a daily life
Most people pay relatively little explicit attention to scent in their daily routine, and pay close attention to it on a few specific occasions. Weddings. Long flights. First days at a new job. The scent of those moments tends to stick. It is one of the more reliable ways the body builds a calendar of itself.
The argument for paying a little more attention to scent across ordinary days is not a perfume-industry argument. It is a memory argument. The smells that surround the unmemorable parts of life are the ones that, decades later, will return entire ordinary mornings. The boring ones, in retrospect, are usually the ones worth keeping.

